Plastic
Introduction
Until the 19th century, mankind used
metals, stones, wood, glass, cotton, etc. to make lifeless possessions like
vehicles, home, furniture and tools. Now, the plastics became a substitute
for all these commodities, and now one see plastic being used in the
manufacture of a wide range of many inanimate belongings.
Classification of Materials
Broadly materials are classified into -
Metals and Non-metals. Metals can be basic metals or alloys. Some of the
major basic metals include iron, copper, aluminum, nickel, gold, silver and
tin. Alloys are homogeneous mixture or solid solution of two or more metals.
For example, brass is an alloy of zinc and copper, while bronze is an alloy
of copper and tin.
Non-metals category comprises materials such as ceramics, polymers, glasses
and fluids. The word 'polymer' gets its origin from Greek word 'polumeros',
meaning consisting of many parts. Polymers can be defined as any of manifold
natural and synthetic blends of typically high molecular weight comprising
of numerous repeated linked units, each of relatively light and simple
molecule. Usually, plastics are organic high polymers, consisting of large
chainlike molecules containing carbon. These are actually formed when the
short-chain molecules of chemicals, monomers, (mono = single + mer = unit)
are hooked together to form large chainlike molecules in the process of
polymerization. If the resulting plastic is made of units of a single
monomer, it's been called as a homopolymer (eg. polyethylene). When the
resulting plastic is made of more than one monomer, then it becomes a
copolymer. Polymers are categorized into -
- Thermosetting
- Thermoplastics
- Elastomers
|
Thermoplastics are those types of polymers
that become soft when heated and hardened when cooled. Thermosetting have
property of becoming permanently hard and rigid when heated or cured.
Thermoplastic scraps can be reused and reprocessed through repeated melting
and solidification by heating and cooling. This is possible because they
consist of long molecules that are not attached or cross-linked to each
other. This is not the case with thermoset plastics as the constituent
molecules are cross-linked. Thermoplastic polymers are usually supplied in
the form of powders or pellets often known as granules/granulates.
Thermosets are often sold in the liquid form or as a partially polymerized
solid molding power. They are shaped into finished forms with or without
pressure by using chemicals or heat when they're in their uncured state.
Elastomers are those polymers that have elastic properties of natural
rubber.
| Types of
Polymers |
Forms |
| Thermosetting |
Alkydes
Diallyl
Phthalates
Melamines
Polyesters
Rigid foam of Urethanes
Rigid foam of Solicons
Others |
| Thermoplastics |
Acetates
Acrylics
Celluosics
Chlorinates
Nylons
Polymides
Polythylenes
Polyprolenes
Vinyls
Others |
| Elastomers |
Acrylates
Flurocarbons
Flurosilicons
Polyrethanes
Polysulfides
Others |
Manufacturers using different processes
transform thermoplastics and thermosets into desirable articles.
| Thermoplastic |
Thermoset |
Extrusion Blow Moulding
Injection Moulding
Rotational Moulding
Injection Blow Moulding
Injection Stetch Blow Moulding
Vaccum Forming
Blown Forming
Structural Foam
Insert Moulding
Cast Film
Post Processing Operations
Other Extrusion Processes |
SMS / DMC Moulding
Compression Moulding
GRP Moulding
Lamination
Pultrusion
Rim
Foam Production |
Manufacturing Process of Plastics
The plastics manufacturing process starts
with refined fractions of oil (naphtha) and or natural gas (ethane) that are
"cracked" to manufacture monomers. The figure given in appendix 1
shows the sequential manufacturing process of plastics.
Uses of Plastics
The role of plastics multiplied with the
rapid industrial development across the globe. It started playing a
predominant role in building industries. The new ideas and innovations in
this modern world made plastics one of the most sought after commodities.
Automobile industry is one of the major users of plastics. A luxury car
possesses around 500 different parts that are made out of plastics. It is
also used for light fittings, upholstery and interior body design of a
modern car. Plastics are known for lightweight, antirust and good insulation
properties. Now-a-days, even glasses are polymeric. These polymeric glasses
are highly popular because of their resilient character.
Another important market where plastic is highly demanded is furniture.
Earlier, only plastic appeared in the form of decorative laminates, but now
full furniture and upholstery are of plastic. Plastic foams replaced cotton,
as they are preferred for their greater durability.
Usage of plastics has increased over years in water and air transport.
Fibreglass boats are vogue because of their lightweight, appearance, lesser
maintenance costs and their anticorrosive property. A product made of
plastic give a consumer what he wants - Safety, performance and Value.
Plastics have almost substituted glassware and crockery. The plastic
bottles are hit because of its shatter-resistance. You get maximum value
from plastics for a minuscule price. They facilitate to make major
appliances, such as refrigerators, washing machines, CTVs and computers,
corrosion resistant, durable and more efficient. They turned out to be a key
element in the modern packaging. They make packaging more efficient, which
eventually protects resources. They are also widely used for vacuum packing.
The role of plastics spread across sectors including medical sciences,
agriculture, fishing and horticulture. They are used as artificial body
parts as replacements to heart valves, bones and teeth. They have their
roots in textiles too. Synthetic fibres are in vogue and are used as
substitutes to the natural fibres - cotton, wool and silk.
The following table shows some of the major uses of
polymer products.
| Type |
Uses |
| LDPE/LLDPE |
Consumer Packaging/Film, Extrusion
Wires, Cable Coatings, etc. |
| HDPE |
Fertilizers, Household Packaging,
Woven Sacks, Cartons, Crates, Luggage, Pipes, etc. |
| Polypropylene (PP) |
Cement Packaging, Monofillament
Yarn, Ropes, etc. |
| PVC |
Water Pipe, Electrical Wires,
Cables, Sheets, etc. |
| Polybutadeine Rubber (PBR) |
Automotive Tyres and Tubes,
Conveyor Belts and Footwear |
Indian Scenario
The per capita consumption of plastics in
India is very low at about 4 kgs per year. The USA and China have an average
consumption at 120 kgs and 17 kgs respectively. The world's average is at 25
kgs per year. The Indian consumption of plastics polymers stood at 4.2
million tonnes in 2003-04. The high incidence of excise duty and sales tax
on plastics restricted the widespread use of plastics in drip irrigation,
agriculture, etc. The consumption of plastics in agriculture is roughly 0.3
lakh tonnes against 20 million tonnes in China. It is estimated that about 3
million jobs are generated by the industry every year. There are about
20,000 plastics processing units (mainly small scale units) in India. The
customs duty in India is higher at 20% as compared to China (7%) and ASEAN
(8%). However, the customs duty may come down shortly, as the government is
required to bring it down the peak customs duty to 10% by 2005 as per WTO
norms. The turnover of the industry was around Rs.28, 000 crores, while the
imports of polymers were about 410,000 tonnes in 2003-04. In the 2004
budget, the excise duties on polymers were raised to 16 percent from 8
percent. The chronology of manufacture of polymers in India:
| Year |
Product |
| 1957 |
Polystyrene |
| 1959 |
LDPE |
| 1961 |
PVC |
| 1968 |
HDPE |
| 1978 |
Polypropylene |
The underlying graph depicts the per capita plastic
consumption of different countries.
Production
Petrochemical industry primarily comprises
of polymers, synthetic fibres, fibre intermediates, elastomers, surfactants,
aromatics and olefins. The industry's production has grown at about 9.5%
annually since 1999-2000. The Indian petrochemical industry made significant
progress in terms of production as well as consumption. There is gradual
decline in the import dependency with the growth in the production of
petrochemical products over the years.
The following table shows the details of production and consumption of
petrochemicals during the years 2001-02, 2002-03 and 2003-04.
| Production
and Consumption of Petrochemicals |
| Figures
in '000 MT |
| |
2001-02 |
2002-03 |
2003-04* |
| Category |
Production |
Consumption |
Production |
Consumption |
Production |
Consumption |
| Synthetic Fibres |
1667 |
1717 |
1755 |
1801 |
1785 |
1900 |
| Polymers |
3974 |
2827 |
4175 |
3795 |
4445 |
4000 |
| Elastomers |
79 |
179 |
81 |
188 |
88 |
190 |
| Surfactants |
425 |
393 |
447 |
391 |
475 |
400 |
| Performance Plastics |
90 |
93 |
95 |
100 |
98 |
105 |
| Total |
6235 |
6206 |
6553 |
6275 |
6891 |
6595 |
* = Estimated
Consumption = Production + Imports - Exports
Polymers include LDPE, LLDPE, HDPE, PP, PS, PVC and Ex. PS
Source: Ministry of Chemicals |
Capacity and Production of Polymers (Actual &
Anticipated)
| Products |
2002-03 |
2003-04 |
2004-05 |
| |
Actual |
Estimated* |
Anticipated |
| Installed
Capacity |
Production |
Installed
Capacity |
Production |
Installed
Capacity |
Production |
| POLYMERS |
| 1. LDPE |
200 |
192 |
200 |
195 |
200 |
200 |
| 2. LLDPE/HDPE |
1520 |
1478 |
1520 |
1500 |
1520 |
1600 |
| 3. PP |
1365 |
1430 |
1365 |
1600 |
1365 |
1750 |
| 4. PS |
414 |
224 |
414 |
270 |
414 |
300 |
| 5. PVC |
780 |
822 |
798 |
850 |
798 |
880 |
| 6.Ex. PS |
37 |
29 |
37 |
30 |
37 |
30 |
| Total |
4316 |
4175 |
4334 |
4445 |
4334 |
4760 |
* : Based on Actual Production reported by the Industrial Units
upto Sept., 2003
Source: Ministry of Chemicals |
Imports & Exports
From a net importer just some years ago,
India has become a net exporter of capital-intensive goods. The country has
emerged as a net exporter in several commodities like steel, copper,
aluminum and plastics. For instance, the country made an exports surplus of
Rs.462 crore in 2003 in plastics from net imports worth Rs.1538 crore seven
years ago. The large capacity additions in the 1990s have changed India from
a net importer to an export surplus country. The import dependency in the
sector has come down to less than 6 percent in recent times from around 60
percent in 1990-91. But, a comparison between China and India reveals that
India exports polymer resin, whereas China imports large quantities of
polymers and exports a variety of value added plastics products. With
flexible labor laws, uninterrupted power supply at competitive cost, lower
interest rates and reduced port handling charges can make the country's
exports more competitive.
| Polymer
Exports from India |
| 1998-99 |
44 |
| 1999-00 |
106 |
| 2000-01 |
368 |
| 2001-02 |
567 |
| 2002-03 |
840 |
Market Structure
Over the last few years, the Indian
Petrochemicals industry has witnessed consolidation phase. The top four
players - Reliance, IPCL, Haldia Petrochemicals (HPL) and GAIL - hold the
majority of the polymer capacity in the domestic market. The IPCL forms a
part of the Reliance group. The external dependence is reduced to a large
extent, with the major players having integrated facilities. For instance,
Reliance Industries makes use of its own Jamnagar refinery as a source for
the petrochemicals production. Alternatively, GAIL uses natural gas for its
petrochemicals production. The lean gas is transmitted to consumers such as
power and fertilizer industry after the separation of hydrocarbons such as
ethane, propane and butane from the rich natural gas.
The raw material costs form nearly 50-60% of the input costs in this
industry. The naphtha is a pricey source of feedstock. The players in the
petrochemical industry have very little bargaining power against the
suppliers. They are all highly vulnerable to raw material prices, which are
highly influenced by nternational demand and supply conditions.
Over the years, the government protected the domestic industry from
overseas competition by imposing heavy import duties. However, of late, the
government has been reducing the import duty steadily on polymers. At
present, the duty is at 20%. The government is likely to cut down the duty
further, as part of its commitment to various multilateral and bilateral
trade agreements. This will likely to expose the domestic players to the
international competition. The domestic industry may have to face global
giants such as Exxon Mobil, Dow Chemicals and Shell in due course of time
with the reduction and elimination of tariff and non-tariff barriers. The
domestic industry may also witness immense competition within with the entry
of IOC and ONGC into the business.
The following are some of the leading raw material manufacturers of India
and abroad.
Domestic Manufacturers
- GAIL
- GE Plastics India
- Haldia Petrochemicals
- IPCL
- Karnataka Petrosynthese Limited
- NOCIL
- Reliance
- Supreme Industries
|
International Manufacturers
- Exxon Mobil
- Honam Petrochemicals
- Hyndai Petrochemicals
- Samsung
- Shell
- Dow Chemicals
|
Price Volatality
The domestic polymer prices show high
variation on a monthly basis. The instability in domestic prices is mainly
derived from the wide variation in international prices and the imported raw
material prices.
| Monthly Variation in Steel Prices between Aug 2002 - Aug 2004 |
| Percentage
Change |
>5 |
2-5 |
<2 |
Max.
Absolute Change (Rs. Per Kg.) |
| No.
of Times |
| PE |
9 |
7 |
9 |
Rs. 8 |
| PP |
3 |
18 |
4 |
Rs. 8.4 |
| PVC |
9 |
12 |
4 |
Rs. 6 |
Historically, the government supported the
domestic players by imposing heavy import duty on the import materials.
However, the government has considerably brought down the customs duty in
the last few years. At present the customs duty is at 20%, while the excise
duty is at 16%. The government is likely to cut the existing duties further
down in the coming years. With these cuts, the competition in this sector
increases with the participation of international giants. The prices are
likely to become more volatile as domestic prices closely follows
international prices. With the liberalized government policy in place, more
number of players is expected to enter, participate and grow in the polymer
industry in the coming days, resulting in higher demand for right pricing
based on indicative markets. There will be a whole lot of producers and
buyers in the production and supply chain whose business is highly dependent
on the right price discovery of the commodity.
| Basic
Prices - Rs. / Kg. |
| Month |
PE |
% Change |
PP |
% Change |
PVC |
% Change |
| Aug-02 |
39.70 |
3.12 |
44.25 |
3.51 |
39.60 |
5.32 |
| Sep-02 |
39.70 |
- |
44.35 |
0.23 |
40.60 |
2.53 |
| Oct-02 |
37.70 |
(5.04) |
42.35 |
(4.51) |
37.60 |
(7.39) |
| Nov-02 |
37.70 |
- |
42.35 |
- |
34.10 |
(9.31) |
| Dec-02 |
37.70 |
- |
42.35 |
2.36 |
36.10 |
5.87 |
| Jan-03 |
41.20 |
9.28 |
48.35 |
11.53 |
42.10 |
16.62 |
| Feb-03 |
43.20 |
4.85 |
50.35 |
4.14 |
43.10 |
2.38 |
| Mar-03 |
46.20 |
6.94 |
51.35 |
1.99 |
43.10 |
- |
| Apr-03 |
43.70 |
(5.41) |
48.85 |
(4.87) |
40.60 |
(5.80) |
| May-03 |
35.70 |
(18.31) |
40.35 |
(17.40) |
34.60 |
(14.78) |
| Jun-03 |
37.20 |
4.20 |
41.35 |
2.48 |
36.10 |
4.34 |
| Jul-03 |
40.20 |
8.06 |
43.35 |
4.84 |
40.50 |
12.19 |
| Aug-03 |
41.00 |
1.99 |
44.35 |
2.31 |
38.50 |
(4.94) |
| Sep-03 |
42.00 |
2.44 |
46.35 |
4.51 |
42.50 |
10.39 |
| Oct-03 |
41.50 |
(1.19) |
44.85 |
(3.24) |
40.50 |
(4.71) |
| Nov-03 |
44.00 |
6.02 |
46.85 |
4.46 |
42.50 |
4.94 |
| Dec-03 |
45.20 |
2.73 |
47.85 |
2.13 |
42.50 |
- |
| Jan-04 |
47.20 |
4.42 |
48.85 |
2.09 |
43.50 |
2.35 |
| Feb-04 |
50.20 |
6.36 |
50.85 |
4.09 |
45.50 |
4.60 |
| Mar-04 |
50.20 |
- |
49.25 |
(3.15) |
47.50 |
4.40 |
| Apr-04 |
49.20 |
(1.99) |
48.25 |
(2.03) |
46.50 |
2.11 |
| May-04 |
49.20 |
- |
48.25 |
- |
47.00 |
1.08 |
| Jun-04 |
50.70 |
3.05 |
49.75 |
3.11 |
47.00 |
- |
| Jul-04 |
51.70 |
1.97 |
51.00 |
2.51 |
46.00 |
(2.13) |
| Aug-04 |
56.20 |
8.70 |
55.70 |
9.22 |
48.00 |
4.35 |